The Portuguese spent three seasons with Wolves, and was the team's top scorer with 17 goals when they secured promotion to the Premier League by winning the Championship in the 2017/18 season.
As expected, head coach Tite also called up Paris Saint-Germain pair Neymar and Marquinhos, Chelsea veteran Thiago Silva, Real Madrid midfielder Casemiro and Barcelona's Philippe Coutinho.
Capped seven times for Brazil's national team, Neves has also had spells with Fluminense, Flamengo and Germany's Hamburg over a career spanning more than 15 years.
"It's not true that I'm not counting on him," insisted Koeman, who believes a loan move is likely.
Reguilon will cost the Spurs 30 million euros, and according to Spanish sports paper Diario AS, has agreed a deal until the end of June 2025 with Real Madrid reserving the right to buy him back for 40 million euros before the summer of 2022.
It added that a meeting would be held with FIFA officials on Tuesday to address issues related to the competition "at the highest level."
With Javi Martinez and Jerome Boateng as possible departure candidates, until the transfer window is closed on October 5, Flick demands replacements.
Celeste head coach Oscar Tabarez named six uncapped players in the squad: Ronald Araujo, Mauro Arambarri, Nicolas De La Cruz, Diego Rossi, Damian Suarez and Rodrigo Munoz.
"I intend to prove my qualities to my critics. This attitude helps me at Schalke get over tough times with my team," the 2015 Belgian champion said.
"Schalke never will be a boring club as emotions have always played a vital role. It makes Schalke unique in football."
Plans about the club's structure will be made in close contact with its 160,000 members who have to vote on any significant changes within the club.